4.5 Article

Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters

Journal

CARBOHYDRATE RESEARCH
Volume 345, Issue 1, Pages 45-49

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2009.09.034

Keywords

Oligosaccharide synthesis; Glycosylation at room temperature; Ionic liquids

Funding

  1. EPSRC
  2. Royal Society
  3. EPSRC [EP/F027222/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/F027222/1] Funding Source: researchfish

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The scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters have been studied. Herein, we report the effects of modifying the structure of the imidazolium cation and how important the choice of counter ion becomes on model glycosylation reactions of thioglycosides at room temperature in the presence of N-iodosuccinimide (NIS). (C) 2009 Elsevier Ltd. All rights reserved.

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