Journal
CARBOHYDRATE RESEARCH
Volume 343, Issue 17, Pages 2863-2869Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2008.06.020
Keywords
Sialyl Lewis x; Sialoside; Oligosaccharide; Chemoenzymatic synthesis
Funding
- NIH [U01CA128442]
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The sialyl Lewis x tetrasaccharide with a propylamine aglycon was assembled by chemoselective glycosylation from a p-tolyl thioglycosyl donor obtained from an enzymatically synthesized sialodisaccharide. Combining the advantages of highly efficient enzymatic synthesis of sialoside building blocks, and diverse chemical glycosylation, this chemoenzymatic approach is practical for obtaining complex sialosides and their analogues. (C) 2008 Elsevier Ltd. All rights reserved.
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