Journal
CARBOHYDRATE RESEARCH
Volume 343, Issue 10-11, Pages 1553-1573Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2008.04.031
Keywords
intramolecular aglycon delivery; glycosylation; tethering; 1,2-cis glycosides; beta-mannosides
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A Minireview with 51 references covering the two-step tethering and intramolecular glycosylation process termed intramolecular aglycon delivery (IAD). Specifically, glycosylation reactions where the tethered oxygen acts as nucleophile are covered. In the majority of cases, tethering to O-2 of a glycosyl donor ensures formation of a 1,2-cis glycoside after intramolecular glycosylation. (C) 2008 Elsevier Ltd. All rights reserved.
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