Journal
CARBOHYDRATE POLYMERS
Volume 101, Issue -, Pages 392-400Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2013.09.066
Keywords
Graphene oxide; Carboxymethyl cellulose; Porous monolith; Metal ion adsorption
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Funding
- National Science Foundation of China [21074089, 21276181]
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Orderly porous graphene oxide/carboxymethyl cellulose (GO/CMC) monoliths were prepared by a unidirectional freeze-drying method. The porous monoliths were characterized by Fourier transform infrared spectra, X-ray diffraction and scanning electron microscopy. Their properties including compressive strength and moisture adsorption were measured. The incorporation of GO changed the porous structure of the GO/CMC monoliths and significantly increased their compressive strength. The porous GO/CMC monoliths exhibited a strong ability to adsorb metal ions, and the Ni2+ ions adsorbed on GO/CMC monolith were reduced by NaBH4 to obtain Ni GO/CMC monolith which could be used as catalyst in the reduction of 4-nitrophenol to 4-aminophenol. Since CMC is biodegradable and non-toxic, the porous GO/CMC monoliths are potential environmental adsorbents. (C) 2013 Elsevier Ltd. All rights reserved.
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