Sorption of carbamazepine from water by magnetic molecularly imprinted polymers based on chitosan-Fe3O4

A novel magnetic-molecularly imprinted polymer (MMIP) based on chitosan-Fe3O4 has been synthesized for fast separation of carbamazepine (CBZ) from water. During polymerization, the modified chitosan-Fe3O4 was used not only as supporter but also as functional monomer. The properties of obtained MMIP were characterized by scanning electron and transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectra, thermo-gravimetric analysis and so on. The sorption equilibrium data was well described by Freundlich isotherm model and the increase in the temperature generated an increase in the sorption amount, indicating endothermic nature of adsorption process. Sorption kinetics followed the pseudo-second-order model. The feasibility of selective sorption of CBZ from real water by the MMIP was analyzed by using spiked real water samples. The result showed that the sorption capacity of MMIP has no obvious decrease in different water samples whereas there was obvious decline in the sorption amount of the MNIP. (C) 2013 Elsevier Ltd. All rights reserved.