Journal
CURRENT ORGANIC SYNTHESIS
Volume 2, Issue 1, Pages 121-145Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570179052996982
Keywords
hypervalent iodine; oxidation; benziodoxole; benziodazole; IBX; DMP
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Five-membered hypervalent iodine heterocycles derived from benziodoxole and benziodazole oxide have recently emerged as reagents of choice for various synthetically useful oxidative transformations. In particular, IBX (2-iodoxylbenzoic acid) and DMP (Dess-Martin periodinane) are widely used for the selective oxidation of primary and secondary alcohols and for a variety of other important oxidations. IBX-amides and IBX-esters are a new class of pentavalent iodine reagents with a pseudo-benziodoxole structure and a reactivity pattern similar to IBX.
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