Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 18, Pages 2366-2368Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b418137a
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We report the unprecedented formation of a benzo-fused 1,3,2-dithiazolylium [AsF6-] salt by a one step, quantitative, cycloaddition of SNSAsF6 with 1,4-benzoquinone. In contrast, the reaction of SNSSbF6 with 1,4-naphthaquinone results in 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium [SbF6-]. Both were reduced to the corresponding 7 pi radicals.
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