Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 48, Pages 5971-5973Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b511809c
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A functional coordination polymer decorated with urea hydrogen-bonding donor groups has been designed for optimal binding of sulfate; self-assembly of a tripodal tris-urea linker with Ag2SO4 resulted in the formation of a 1D metal - organic framework that encapsulates SO42- anions via twelve complementary hydrogen bonds, which represents the highest coordination number observed for sulfate in a natural or synthetic host.
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