Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 16, Pages 2172-2174Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b501778e
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The selectivity of the iridium boryl complex-catalysed reaction of pyrene and perylene with B-2(pin)(2) (pin = OCMe2CMe2O) has been employed in the synthesis of D-2h-symmetry pyrene-2,7-( Bpin)(2) and D-4h-symmetry perylene-2,5,8,11-(Bpin)(4) providing direct borylation of positions which are otherwise difficult to derivatise.
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