4.7 Article

Metal-directed ring-expansion in Schiff-base polypyrrolic macrocycles

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 35, Pages 4423-4425

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b507729j

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The reaction between a [2 + 2] Schiff-base porphyrin analogue and zinc acetate results in the unusual formation of an enlarged [3 + 3] macrocycle that is stabilised by metal coordination and intramolecular hydrogen-bonding interactions.

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