4.7 Article

Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 40, Pages 5044-5046

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b508468g

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Pure enantiomers of a polytungstate cluster [(alpha-P2W16O59)Zr-2(mu 3-O)(mal)](2)(18-) (mal = malate) have been obtained and their conversion to meso diastereomers was observed by P-31 NMR.

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