4.8 Article

Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 44, Issue 27, Pages 4209-4212

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.200500784

Keywords

asymmetric catalysis; hydrogenation; ligand effects; phosphines; rhodium

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