Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 7, Pages 924-926Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b414423f
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Chemoselective hydrogenation of halogenated nitrobenzenes over Pt/C catalysts proceeds effectively in supercritical carbon dioxide (scCO(2)) to produce halogenated anilines with excellent selectivity; the rate of the hydrogenation of nitro groups is markedly enhanced in scCO(2) compared to the neat reaction, and the dehalogenation reaction is significantly suppressed.
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