4.7 Article

Cross-coupling of benzylic acetates with arylboronic acids: one-pot transformation of benzylic alcohols to diarylmethanes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 47, Pages 5899-5901

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/B513372F

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Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(eta(3)- C3H5)Cl](2) catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields ( up to 94% isolated yield).

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