4.7 Article

Benzene C-H activation by platinum(II) complexes of bis(2-diphenylphosphinophenyl)amide

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 19, Pages 2462-2464

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b501520k

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The amido diphosphine complexes [PNP]PtMe and [PNP]PtOTf, where [PNP](-) is bis(2-diphenylphosphinophenyl)-amide, effectively activate the benzene C-H bond in the presence of an appropriate Lewis acid or base, leading to the formation of [PNP]PtPh quantitatively.

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