4.7 Article

Regioselective allylgallation of terminal alkynes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 14, Pages 1874-1876

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b417975g

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The reactions of terminal alkynes with allylgallium reagents generated in situ from gallium and allyl bromides gave the corresponding 1,4-dienes in good yield via Markovnikov addition in THF at 70 degrees C.

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