4.7 Article

A readily prepared neutral heterobimetallic titanium(IV)-rhodium(I) catalyst for intramolecular hydroacylation

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 26, Pages 3307-3309

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b504195c

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The combination of HOCMe2CH2PPh2, Ti(OiPr)(4), and [Rh(cod)Cl](2) ( 3: 1: 1) in either benzene or dichloromethane produces a discrete species ( tentatively formulated as complex 14) that is an active catalyst for intramolecular hydroacylation reactions of 3-substituted pentenals.

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