Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 22, Pages 2855-2856Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b503686k
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Nucleophilic addition of an organorhodium( I) to a cyano group has been observed for the first time in the rhodiumcatalysed reaction of cyano-substituted alkynes with arylboronic acids. The higher reactivity of a cyano group relative to an alkoxycarbonyl group toward an organorhodium(I) species is demonstrated by an intramolecular example.
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