4.7 Article

The first high oxidation state manganese-calcium cluster: relevance to the water oxidizing complex of photosynthesis

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 1, Pages 54-56

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b413680b

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Synthetic entry has been achieved into high oxidation state Mn - Ca cluster chemistry with the preparation of [Mn13Ca2O10(OH)(2)(OMe)(2)(O2CPh)(18)(H2O)(4)]; the structure contains [Mn4CaO4] sub-units similar to that found in the photosynthetic water oxidizing complex.

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