Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 20, Pages 2627-2629Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b418789j
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UV irradiation of fluorinated TiO2 suspensions in water, in the presence of oxygen and a hole scavenger, leads to the production of H2O2 with steady state concentration levels up to 1.3 millimolar; the H2O2 formation rate follows the TiO2 surface speciation, being maximum when the surface is completely covered by =Ti - F groups; these results outline the importance of surface speciation on the photocatalytic process.
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