Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 42, Pages 5301-5303Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b508004e
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The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where 1 is [Fe(II)(BPMEN)(CH3CN)(2)](ClO4)(2) and BPMEN = N,N'-dimethyl-N,N'-bis(2-pyridylmethyl)ethane-1,2- diamine); the product of this reaction is a novel mononuclear iron(III) complex with a chelating salicylate.
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