Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 152, Issue 4, Pages A774-A777Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.1867652
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In situ spectroscopic ellipsometry was employed to study the initial stage of solid electrolyte interphase (SEI) layer formation on thin-film LiMn2O4 electrodes. The SEI layer formed immediately upon exposure of the electrode to ethylene carbonate/dimethyl carbonate (1:1 by vol) 1.0 M LiPF6 electrolyte. The SEI layer thickness then increased in proportion to a logarithmic function of elapsed time. In comparison, the SEI layer thickness on a cycled electrode increased in proportion to a linear function of the number of cycles. (c) 2005 The Electrochemical Society.
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