Discoloration and mineralization of Orange II by using a bentonite clay-based Fe nanocomposite film as a heterogeneous photo-Fenton catalyst

Discoloration and mineralization of an azo dye Orange II was conducted by using a bentonite clay-based Fe nanocomposite (Fe-B) film as a heterogeneous photo-Fenton catalyst in the presence of UVC light and H2O2. Under optimal conditions (pH = 3.0, 10mM H2O2, and 1 x 8W UVC), 100'% discoloration and 50-60% TOC removal of 0.2 mM Orange II can be achieved in 90 and 120 min, respectively. The mineralization kinetics of 0.2 mM Orange II is much slower than the corresponding discoloration kinetics. Under the same conditions, the Fe leaching from the Fe-Bcoated catalyst film is very low. The Fe-B-coated catalyst film could be used in the pre-treatment of wastewater for an integrated system consisting of a photochemical reactor and a biological reactor. Multi-run experimental results reveal that the Fe-B-coated catalyst film could have a long-term stability for the discoloration and mineralization of Orange II. A comparison between the performance of the Fe-B-coated catalyst film and a suspended Fe-B catalyst in the discoloration and mineralization of Orange II was also discussed. (C) 2004 Elsevier Ltd. All rights reserved.