Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 3, Issue 8, Pages 1362-1364Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b500618j
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An approach to asymmetric catalysis based on chiral molecular recognition by the combination of chiral Lewis acids and chiral organocatalysis for the formation of optically active quarternary centers in the aza-Henry reaction is presented; this procedure leads to products with up to 98% ee and a diastereomeric ratio of 14 : 1 in excellent yields with catalyst loadings of 5 mol%.
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