Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 631, Issue 15, Pages 3096-3099Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200500296
Keywords
cobalt; methyl complexes; salicylaldimine; trimethylphosphine; crystal structure
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Dimethyl(salicylaldiminato[N:O])cobalt complexes [CoMe2(2-O-(C6H1RRR3)-R-1-R-2-CH=NR4)L-2] (L=PMe3) (1 - 6) have been prepared through the reaction of.[CoMe3(PMe3)(3)] with the corresponding substituted salicylaldimine. The complexes were characterized with IR, H-1 NMR, C-13 NMR, P-31 NMR and elemental analyses. The X-ray crystal structure of complex I shows an octahedral coordination of cobalt, with two equatorial cis-methyl groups opposite to the planar N:O-chelate ring.
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