4.3 Article

Synthesis of rigid polyaromatic dialdehydes

Journal

SYNTHETIC COMMUNICATIONS
Volume 35, Issue 2, Pages 161-167

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-200048397

Keywords

rigid dialdehydes; Suzuki-Miyaura cross-coupling; terphenyl derivatives

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Rigid polyaromatic dialdehydes: biphenyl-4,4'-dialdehyde and its longer analogues have been synthesized in high yields by using the Suzuki-Miyaura cross-coupling reaction. In addition, a novel procedure for a gram-scale preparation of biphenyl-4,4'-dicarbaldehyde from commercially available 4,4'-bis(chloromethyl)biphenyl has been developed.

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