Journal
CRYSTAL GROWTH & DESIGN
Volume 5, Issue 1, Pages 373-377Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cg049864c
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An o-phenylenediamine-bisguanidine derivative, o-phenylenebis(N,N'-dimethyl-N,N'-ethylene)guanidine (BG), was designed as a powerful hydrogen acceptor. The complexation of BG with a variety of hydrogen donor aromatics carrying OH groups such as benzoic acid (BA), phenol (PH), and benzyl alcohol (BAL) led to the successful isolation of the expected 1 + 1 crystalline complexes, regardless of the acidity of the hydrogen donors. In the case of BA, additional 1 + 2 and 1 + 4 BG-BA crystalline complexes were formed under rigorous conditions of stoichiometry-controlled complexation. These crystals were fully characterized by X-ray crystallographic analysis, indicating that nonbonded interactions in addition to N-H hydrogen bonding play an important role during the crystallization process. Mutual interconversion among the BG-BA crystalline complexes was achieved by the addition of either component to the original complex. Thus, BG was found to act as a powerful hydrogen acceptor in hydrogen bond-based complexation with hydrogen donor aromatics.
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