4.3 Article

Iodic acid (HIO3) in combination with tetraethylammonium bromide as a catalyst for selective and accelerated sulfoxidation

Journal

SYNTHETIC COMMUNICATIONS
Volume 35, Issue 21, Pages 2805-2810

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/00397910500290540

Keywords

iodic acid; sulfides; sulfoxides; tetraethylammonium bromide (TEAB)

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The article describes the use of iodic acid in combination with catalytic amounts of tetraethylammonium bromide (TEAB) as a mild and alternative reagent system for oxidation of sulfides to sulfoxides. The salient features of the developed system are room-temperature reactions, short reaction times, and compatibility with a wide range of functional groups.

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