Laminar and unstable burning velocities and Markstein lengths of hydrogen-air mixtures at engine-like conditions

Hydrogen offers an attractive alternative to conventional fuels for use in spark ignition engines. It can be burned over a very wide range of equivalence ratios and with considerable exhaust gas recirculation. These help to minimise pumping losses through throttleless operation and oxides of nitrogen (NOx) production through reduced temperature. Full understanding of hydrogen-fuelled engine operation requires data on the laminar burning rate of hydrogen-air residuals under a wide range of conditions. However, such data are sparse. The present work addresses this need for experimental data. Spherically expanding H-2-air flames were measured at a range of temperatures, pressures, and equivalence ratios and with varying concentrations of residuals of combustion. Unstretched burning velocities, u(1), and Markstein lengths, L-b, were determined from stable flames. At the higher pressures, hydrodynamic and diffusional-thermal instabilities caused the flames to be cellular from inception and prohibited the derivation of values of u(1) and L-b. The effect of pressure on the burning rate was demonstrated to have opposing trends when comparing stoichiometric and lean mixtures. The present measurements were compared with those available in the literature, and discrepancies were attributed to neglect, in some works, the effects of stretch and instabilities. From the present measurements, the effects of pressure, temperature, and residual gas concentration on burning velocity are quantified for use in a first step towards a general correlation. (c) 2004 The Combustion Institute. Published by Elsevier Inc. All rights reserved.