Autogenous shrinkage of concrete: a balance between autogenous swelling and self-desiccation

According to physical analyses, the driving force of autogenous shrinkage of concrete is the change in the capillary pressure induced by self-desiccation in its cement matrix. Self-desiccation is caused by the balance between the absolute volume reduction (chemical shrinkage) and the building up of the capillary network. The aim of this study was to quantify the influence of the cement characteristics on the chain of mechanisms leading from hydration to autogenous deformations. Four parameters were selected: (i) for clinker, the amount Of C(3)A and free lime and the SO3/K2O ratio; (ii) for cement, the fineness. To master the experimental area, 16 cements were prepared at the laboratory from pure raw materials. An important number of characterizing techniques were used in the experimental study. Their choice was based on the important parameters drawn from the physical analysis: setting time, suspension-solid transition, hydration kinetics through isothermal calorimetry and nonevaporable water, chemical shrinkage, evolution of relative humidity, capillary porosity and autogenous shrinkage. Using different techniques allowed to determine the precise mechanism of action of each parameter. Results showed that these mechanisms are generally different, even if their macroscopic consequences may be identical. This point will probably be useful for modeling and determining the industrial keys reducing the autogenous shrinkage. The physical mechanisms involved in autogenous deformations were further understood. In particular, this study shows that initial autogenous shrinkage should be considered as a balance between the self-desiccation and an initial swelling phase. The influence of the four parameters considered on this last phenomenon were also characterized. (C) 2004 Elsevier Ltd. All rights reserved.