Journal
NUCLEOSIDES NUCLEOTIDES & NUCLEIC ACIDS
Volume 24, Issue 5-7, Pages 513-518Publisher
TAYLOR & FRANCIS INC
DOI: 10.1081/NCN-200061786
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The first total chemical synthesis of nicotinamide adenine dinucleotide phosphate (P-NADP, 2) as a single isomer was achieved. Thin was subsequently converted into the important second messenger nicotinic acid adenine dinucleotide phosphate (P-NAADP) 1 and the identity of this material confirmed by biological evaluation. This flexible synthetic route offers new opportunities for the generation of NAADP I analogues that cannot be generated directly from NADP 2 or mainly enzymatic methods.
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