Journal
ARKIVOC
Volume -, Issue -, Pages 39-48Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0006.e05
Keywords
N-heterocyclic carbene; L-proline; chiral; arylboronic acid; aldehyde
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Novel chiral imidazolium salts and a stable N-heterocyclic carbene-Rh complex derived from L-proline have been synthesized. The N-heterocyclic carbene-Rh complexes either generated in situ or pre-synthesized are active catalysts for the addition reaction of arylboronic acids to aldehydes affording the corresponding secondary alcohols in excellent yields.
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