Journal
GREEN CHEMISTRY
Volume 8, Issue 4, Pages 338-343Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b517152k
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Palladium(II)-catalyzed oxidative Heck arylation reactions proceed at room temperature with atmospheric air as the sole reoxidant. Using arylboronic acids as arylating agents and inexpensive 2,9-dimethyl-1,10-phenanthroline as the supporting ligand, efficient vinylic substitution reactions were obtained both with electron-poor and electron-rich olefins on a 1 - 50 mmol scale.
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