4.4 Article

Liquidus curves of NH4NO3 (aq) calculated from the modified adsorption isotherm model for aqueous electrolytes

Journal

SEPARATION SCIENCE AND TECHNOLOGY
Volume 41, Issue 11, Pages 2629-2634

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/01496390600743045

Keywords

activity coefficients; aqueous electrolyte; Brunauer-Emmett-Teller (BET); absorption isotherm; eutectic

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The Stokes-Robinson modification of the Brunauer-Emmett-Teller (BET) adsorption isotherm is used to calculate the liquidus curve of NaNO3 (aq) including the eutectic point and metastable phases. The method described here represents a simplified approach to predict the liquidus curves with sparse information and considers the presence of several crystalline solid phases of NH4NO3 .

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