4.2 Article Proceedings Paper

High-quality lead-free ferroelectric ceramics prepared from the flash-creation-method-derived nanopowder

Journal

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
Volume 114, Issue 1325, Pages 97-101

Publisher

CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI
DOI: 10.2109/jcersj.114.97

Keywords

ferroelectric; lead-free; bismuth titanate; BLT; nanopowder

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We report high-quality and high-density Bi3.25La0.75Ti3O12 ceramics prepared by sintering at a low temperature of 900 degrees C from the nanosized powder with a diameter around 100 nm synthesized by the flash creation method. The densification at 900 degrees C, which was 300 degrees C lower sintering temperature compared with conventional solid-state reaction, enables us to obtain the ceramics showing a remanent polarization of 14.5 mu C/cm(2), a coercive field of 50 kV/cm and a leakage current of similar to 10(-9) A /cm(2). The superior properties are indicated to originate from lower defect concentration achieved by the low temperature sintering.

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