4.4 Article

Combination vs. disproportionation in dialkyl biradicals. Selectivity reversal in a crystalline solid

Journal

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
Volume 5, Issue 5, Pages 449-451

Publisher

SPRINGERNATURE
DOI: 10.1039/b603909j

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While 1,6-biradicals produced by photodecarbonylation of dimethyl 11-oxodibenzo[c,h]bicyclo[4.4.1]undeca-3,8-diene-1,6-dicarboxylate (1) react exclusively by disproportionation in benzene solution, reactions in crystals lead to radical radical combination reactions in almost quantitative yield.

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