Distribution of natural radionuclides in the production and use of phosphate fertilizers in Brazil

The Brazilian phosphate fertilizer is obtained by wet reaction of igneous phosphate rock with concentrated sulphuric acid, giving as final product, phosphoric acid and dehydrated calcium sulphate (phosphogypsum) as by-products. Phosphoric acid is the starting material for triple superphosphate (TSP), single superphospbate (SSP), monoammonium phosphate (MAP) and diammonium phosphate (DAP). The phosphate rock used as raw material presents in its composition radionuclides of the U and Th natural series. Taking this into account, the main aim of this paper is to evaluate the fluxes of natural radionuclides and radioactive disequilibria involved in the Brazilian industrial process of phosphoric acid production; to determine the content of radioactivity in several commercial fertilizers produced by this industry; to estimate their radiological impact in crop soils and the long term exposure due to their application. Radiological characterization of phosphate rock, phosphogypsum and phosphate fertilizers was performed by alpha and gamma spectrometry. The fertilizer samples, which are derived directly from phosphoric acid, MAP and DAP, presented in their composition low activity concentrations for Ra-226, Ra-228 and Pb-210. As for U and Th, the concentrations found in MAP and DAP are more significant, up to 822 and 850 Bq kg(-1), respectively. SSP and TSP, which are obtained by mixing phosphoric acid with different amounts of phosphate rock, presented higher concentrations of radionuclides, up to 1158 Bq kg(-1) for U-238, 1167 Bq kg(-1) for U-234, 1169 Bq kg(-1) for Th-230, 879 Bq kg(-1) for Ra-226, 1255 Bq kg(-1) for Pb-210, 521Bq kg(-1) for Th-232, (246)Bq kg(-1) for Ra-228 and 302 Bq kg (-1) for Th-228. Long term exposure due to successive fertilizer applications was evaluated. Internal doses due to the application of phosphate fertilizer for 10, 50 and 100 years were below 1 mSv y(-1), showing that the radiological impact of such practice is negligible. (c) 2006 Elsevier Ltd. All rights reserved.