Journal
MATERIALS & DESIGN
Volume 27, Issue 10, Pages 1120-1127Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2005.03.015
Keywords
INCONEL alloy 740; microstructure stability; corrosion resistance; thermodynamic calculation
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INCONEL alloy 740 is a newly developed Ni-Cr-Co-Mo-Nb-Ti-Al superalloy in the application to ultra-supercritical boilers with steam temperatures up to 700 degrees C. By means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), micro-chemical phase analyses, and corrosion-resisting test, this paper investigates the structure stability of the alloy at elevated temperature and concentrates on coal ash corrosion performance of the alloy under the simulated coal ash/ flue gas condition. Experimental results show that the most important structure instabilities of the alloy during prolonged aging are gamma' coarsening, gamma' to eta transformation and G phase formation at grain boundary. The performance of corrosion resistance of the alloy would meet the requirement of ultra-supercritical boiler tubes. The phase computation by means of Thermo-Calc has been adopted in chemical composition modification for structure stability improvement. Two suggested new modified alloys in adjustment of the Al and Ti contents and in control of Si level, and also in maintenance of Cr content of the alloy were designed and melted for experimental investigation. These two modified alloys exhibit more stable microstructure during 760 degrees C long time aging. (C) 2005 Published by Elsevier Ltd.
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