4.7 Article

Hybrid superaggregate morphology as a result of aggregation in a cluster-dense aerosol

Journal

PHYSICAL REVIEW E
Volume 73, Issue 1, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.73.011404

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From the digitized pictures of soot clusters formed after the explosion of a hydrocarbon gas mixed with oxygen, the cluster morphology was determined by two different methods: structure factor and perimeter analysis. We find a hybrid, superaggregate morphology characterized by a fractal dimension of D approximate to 1.8 between the monomer size, ca. 50 nm, and 1 mu m and D approximate to 2.6 at larger length scales up to similar to 10 mu m. The superaggregate morphology is a consequence of late-stage aggregation in a cluster-dense regime near a gel point.

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