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Experimental evidence for linear metal-azido coordination: The binary Group 5 azides [Nb(N(3))(5)], [Ta(N(3))(5)], [Nb(N(3))(6)](-), and [Ta(N(3))(6)](-) and 1 : 1 acetonitrile adducts [Nb(N(3))(5)(CH(3)CN)] and [Ta(N(3))(5)(CH(3)CN)]

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Volume 45, Issue 29, Pages 4830-4835

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WILEY-BLACKWELL

DOI: 10.1002/anie.200601060

Keywords

azides; density functional calculations; niobium; tantalum; vibrational spectroscopy

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Experimental evidence for linear metal-azido coordination: The binary Group 5 azides [Nb(N(3))(5)], [Ta(N(3))(5)], [Nb(N(3))(6)](-), and [Ta(N(3))(6)](-) and 1 : 1 acetonitrile adducts [Nb(N(3))(5)(CH(3)CN)] and [Ta(N(3))(5)(CH(3)CN)]

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Publisher

WILEY-BLACKWELL

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Experimental evidence for linear metal-azido coordination: The binary Group 5 azides [Nb(N(3))(5)], [Ta(N(3))(5)], [Nb(N(3))(6)](-), and [Ta(N(3))(6)](-) and 1 : 1 acetonitrile adducts [Nb(N(3))(5)(CH(3)CN)] and [Ta(N(3))(5)(CH(3)CN)]

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Publisher

WILEY-BLACKWELL

Keywords

Categories

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