Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 2, Pages 186-188Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b510795d
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Fluorescence signaling in anion binding is modulated from quenching to enhancement by intramolecular H-bonding stabilization of anion-ionophore adducts; the intramolecular H-bonding is suggested to suppress the quenching processes otherwise possible and increase the conformational rigidity of the anionic adducts, leading to fluorescence enhancement in a selective fashion towards cyanide ion, among the various anions examined.
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