4.7 Article

Stereoselective polymerization of rac- and meso-lactide catalyzed by sterically encumbered N-heterocyclic carbenes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 27, Pages 2881-2883

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b601393g

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New sterically encumbered N-heterocyclic carbene catalysts were synthesized and used to polymerize rac-lactide to give highly isotactic polylactide or meso-lactide to give heterotactic polylactide.

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