4.7 Article

First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 45, Pages 4747-4749

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b611823b

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A new organocatalytic system, novel chiral bisformamide 3 and in situ generated L-proline-derived allylsilane reagent 14', which converts different aldimines to homoallylic amines in good to high yields (up to 95%) and good enantioselectivities (up to 85% ee) has been described.

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