Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 43, Pages 4498-4500Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b606689e
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EB ( electron beam) irradiation of sulfonamide within a beta-cyclodextrin (beta-CD) inclusion complex in the solid state induced the solvent-free Fries rearrangement, which proceeded at a shorter reaction time with reversed regioselectivity by inclusion into the beta-CD, compared with that of sulfonamide crystals; the beta-CD as a restricted nanospace had a large effect on the reactivity and regioselectivity of the solvent-free EB-Fries rearrangement.
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