Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 15, Pages 1625-1627Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b600812g
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In situ crystallography reveals that the solid state [2 + 2] photodimerization of acenaphthylene in a coordination cage takes place smoothly without preorganizaiton of reaction centers at a preferred geometry, because the substrate tumbles thermally in the large hollow of the cage.
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