Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 38, Pages 3981-3983Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b609556a
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The biosynthetic pathway to 4-methoxy-2,2'-bipyrrole-5-carboxaldehyde (MBC), a key intermediate in the biosynthesis of prodiginine antibiotics in Streptomyces coelicolor, has been elucidated using a combination of gene replacements and feeding experiments with chemically synthesised MBC and a synthetic analogue of a pathway intermediate.
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