4.7 Article

GaCl3-assisted [2+3] cycloaddition: A route to tetrazaphospholes

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 11, Pages 1236-1238

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b517459g

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The GaCl3-assisted [2 + 3] cycloaddition of Mes*-N=P-Cl (Mes* = 2,4,6-(Bu3C6H2)-Bu-t) with trimethylsilylazide (TMS-N-3) results in the formation of the first tetrazaphosphole, stabilized as a GaCl3 adduct in high yields (> 96%).

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