4.7 Article

Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 31, Pages 3332-3333

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b606311j

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A strained 1-phenyl-2,3-dimethylphosphirene undergoes anionic ring-opening polymerization upon initiation with n-butyl lithium at ambient temperature to yield polyvinylenephosphine, an unsaturated organophosphorus polymer.

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