Structure and lattice dynamics of binary lead silicate glasses investigated by infrared spectroscopy

The polar lattices dynamics of seven binary lead silicate glasses have been studied by infrared spectroscopy. The analysis of the reflectivity spectra with a dielectric function model, based on a modified Gaussian profile, allows a quantitative evaluation of the presence of lead cations within different structural sites. From the role of the lead cations versus the degree of polymerization of the silicate network and the comparison with literature results, we may to give a scenario for explaining the observed structural evolution of the glass matrix and more particularly the drastic change occurring around 45% of lead content. Below this threshold, lead cations act only as modifiers of the silicate network. Above, the glass structure is deeply modified; a lead network involving around 10% of the lead content appears in glasses whose composition is just above the threshold and progressively grows at the expense of the silicate network with the increase of lead content. For high lead content, lead cations can act as modifiers of the silicate network or as network formers. Results also show that the analysis of far infrared measurements combined with the knowledge of the UV edge optical response is very promising to characterize the local disorder around cations in glasses. (c) 2006 Elsevier B.V. All rights reserved.