Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 12, Issue 2, Pages 429-437Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200500837
Keywords
cations; phase-transfer catalysis; phosphazenes; phosphorus
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A series of peralkylated polyaminophosphazenium cations exhibiting extraordinary base resistance under phase-transfer conditions were efficiently synthesized from readily available starting materials. Their half lives under these conditions exceed those of the most stable conventional organic cations by factors of up to 3000.
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